Solidification/stabilization and optimization of municipal solid waste incineration fly ash with aluminosilicate solid wastes.

Alkali-activation is an effective municipal solid waste incineration fly ash (MSWIFA) solidification/stabilization (S/S) technology. However, the characteristics of calcium-rich silica-poor aluminum phase in MSWIFA easily cause the structural instability and contamination of alkali activated MSWIFA S/S bodies. Therefore, the aluminosilicate solid wastes are used in this work to optimize the immobilization and structural properties. Results showed that incorporation of aluminosilicate solid wastes significantly improved the compressive strength and heavy metals pollution toxicity of MSWIFA S/S bodies. Compared to alkali activated MSWIFA, the compressive strength of S/S bodies with addition of coal fly ash, silica fume and granulated blast furnace slag improved by 31.0%, 47.6% and 50.8% when the curing time was 28 days, respectively. Leachability of Pb, Zn and Cd in these alkali activated MSWIFA S/S bodies was far below the threshold value specified in Standard GB16889. Aluminosilicate solid wastes provided abundant Si/Al structural units, and some new phases such as ettringite(AFt, 3CaO⋅Al2O3⋅3CaSO4⋅32H2O), calcium sulfoaluminate hydrate (3CaO⋅Al2O3⋅CaSO4⋅12H2O) and Friedel's salt (CaO⋅Al2O3⋅CaCl2⋅10H2O) can be detected in S/S matrix with aluminosilicate solid wastes, along comes increased the amount of the amorphous phases. Lower Ca/Si molar ratio tended to form the network structure gel similar to tobermorite with higher polymerization degree. Meanwhile, the silica tetrahedron of the gels changed from the oligomerization state like island to the hyperomerization state like chain, layer network or three-dimensional structure, and average molecular chain length increased. These findings provide theoretical basis for structural properties optimization and resource utilization of MSWIFA S/S matrices.

Wood fly ash and blast furnace slag management by alkali-activation: Trace elements solidification and composite application.

Wood and biomass are burned in many industries as a sustainable energy source. The large quantities of fly ash produced must be landfilled, leading to environmental concerns. Precipitator wood fly ash (PFA) and ground granulated blast furnace slag (BFS) have been used in this study to prepare alkali-activated composites to manage and recycle the fly ash. After an essential characterization, the influence of parameters such as PFA and BFS content, alkaline activator content (silica moduli of 0, 0.82, 1.32), curing method, and curing duration on the mechanical, chemical, and microstructural properties of the samples have been studied through compressive strength, density, FTIR, and SEM-EDS investigations. The environmental safety and influence of polycondensation on heavy metal stabilization have been examined through ICP-MS. The results prove that oven and hydrothermal curing obtain the early age strength. Despite the variations of strength with duration and type of curing, the compressive strength of samples after 28 days of curing tends to close values for a constant PFA/BFS ratio, due to which the need for energy-intensive curing methods is addressed. ICP-MS shows that the composites can suitably solidify As, Cd, Ba, Cr, Pb, Mo, Se, Hg, Sr, Cu, and Zn. On the other hand, the composites were almost incapable of stabilizing Co and V. Unlike the case for mechanical properties; higher PFA content favours hazardous metal stabilization through polycondensation.

Thermal treatment of alkali lignin to eliminate its inhibition of pancreatic proteases in vitro.

This study aims to investigate how alkali lignin inhibits protein digestion and explore thermal treatment as a potential solution. Solid alkali lignin species pre-heated at different temperatures (150, 200, and 250 °C) and soluble acid-differentiated fractions are subjected to in vitro protein digestion. A range of techniques, including Thermogravimetric Analysis (TGA), Size-Exclusion Chromatography (SEC), Zeta Potential Analyzer, 1H NMR, Isothermal Titration Calorimetry (ITC), and Molecular Docking, were used to investigate the inhibitory mechanism of alkali lignin on pancreatic proteases hydrolysis. Our results suggest that soluble alkali lignin inhibits pancreatic trypsin and chymotrypsin, with the acid-differentiated soluble fraction (LgpH<1) displaying the strongest inhibition and proteases' binding affinity due to the abundance of polar groups (e.g., -OH, -CHO), which facilitate hydrogen-bond formation. Furthermore, pre-heating lignin (200 °C) was confirmed effective for removing LgpH<1 and its negative nutritional influence, providing a feasible strategy for overcoming the negative impact of alkali lignin on protein digestion.

Solidification of municipal solid waste incineration fly ash with alkali-activated technology.

Alkali-activation is effective municipal solid waste incineration fly ash (MSWIFA) solidification/stabilization (S/S) technology. Percolation and migration of heavy metals in MSWIFA S/S matrix is a complicated and slow process. Here, several alkali-activated MSWIFA samples are selected to comparatively investigate the long-term leaching behavior and environmental availability of Pb, Zn and Cd when exposed in different erosion environment. Acid environment posed the more serious destroy to MSWIFA S/S matrices. RAC demonstrated that potential risk level of heavy metals is higher in acid rain environment, and Cd, Zn showed the prominent risk. When soaked in acid rain solution, the surface of alkali-activated MSWIFA S/S matrices was cracked seriously and a large number of hardened slurry peeled off. However, more stable structural properties and lower heavy metal leachability can be found in alkali-activated MSWIFA/aluminosilicate. The immobilization efficiency of Pb, Zn and Cd were all above 99.0%. Microstructure and morphology results indicated that there is new phase Friedel's salts generated and much more amorphous substance such as C-(A)-S-H gel with incorporation of aluminosilicate, which all contributed much to the formation of compact and stable microstructure, then significantly facilitated the encapsulation of heavy metal. These findings will provide theoretical basis and new insight for resource utilization and security landfill of MSWIFA.

Extraction of W, V, and As from spent SCR catalyst by alkali pressure leaching and the pressure leaching mechanism.

Spent selective catalytic reduction (SCR) catalysts are environmentally hazardous and resource-enriching. In this work, V, W, and As in a spent SCR catalyst was extracted by alkali pressure leaching. Results showed that the V, W, and As were loaded on the anatase TiO2 crystal grains as amorphous oxides. The optimum pressure leaching conditions were NaOH concentration of 20 wt%, reaction temperature of 180 °C, reaction time of 120 min, L/S of 10 mL/g, and stirring speed of 300 rpm. The leaching efficiency of W, V, and As reached 98.83%, 100%, and 100%, respectively. The experiment revealed the preferential leaching of V and As rather than W, and the leaching mechanisms of V, W, and As were studied through experiment and density functional theory (DFT). The leaching kinetics of W conformed to a variant of the shrinking core model and the leaching process of W is controlled by both chemical reactions and diffusion processes. During the leaching process, Na2Ti2O4(OH)2 product powder layer was generated, which affects the mass transfer of W. The destruction of the TiO2 skeleton in the spent SCR catalyst is essential for adequate W extraction, especially for the extraction of W embedded in the TiO2 lattice. The DFT simulation result indicated that the V and As loaded onto the TiO2 support are easier to absorb hydroxide ions rather than W, and the leaching reaction energy of V and As was lower than W, As, and V has leaching priority over the leaching of W. Furthermore, an anatase TiO2 photocatalyst with the {001} crystal surface exposed was successfully prepared from the alkali pressure leaching residue. This work provides theoretical support for the metal leaching and utilization of spent SCR catalysts via alkali pressure leaching.

Wind erosion control using alkali-activated slag cement: Experimental investigation and microstructural analysis.

This paper aims to mitigate wind erosion of soil by employing alkali-activated slag. Wind tunnel tests were conducted on soil samples treated with varying percentages of slag at different wind speeds (7, 14, 21, and 28 m/s) and under a sand bombardment condition. In the absence of saltating particles, the erodibility ratios of the alkali-activated slag-treated samples with weight percentages of 1%, 2%, 4%, and 6% to the untreated sample at the highest wind speed (i.e., 28 m/s) correspond to 0.19%, 0.10%, 0.08%, and 0.06%, respectively. Moreover, in the presence of saltating particle bombardment, these samples exhibited erodibility reductions of 98.5%, 98.8%, 99.4%, and 99.6% compared to the untreated sample. The strength of the formed crusts, determined by penetrometer tests, increased significantly for the treated samples, ranging from 1300 to 6500 times greater than the untreated sample. The complementary analysis using x-ray diffraction and field emission scanning electron microscopy revealed the formation of albite and anorthite crystals along with the formation of calcium aluminosilicate hydrate, sodium aluminosilicate hydrate, and calcium silicate hydrate gels in the cementation process. Overall, the study highlights the effectiveness of alkali-activated slag in forming strong crusts that provide substantial protection against wind erosion, resulting in a significant decrease in wind erodibility.

Upcycling sulphidic copper tailings into alkali-activated slag materials: effect of the sulfur content.

Sulfidic copper tailings (SCTs) with excessive sulfur content are prone to oxidation, leading to the generation of sulfates and causing compatibility issues with cement. To address this problem, this paper proposes upcycling SCTs into alkali-activated slag (AAS) materials to fully utilize the produced sulfates for slag activation. The influence of the sulfur content of the SCTs compound (quartz, SCTs, and fine pyrite) on the properties of AAS was investigated from various aspects including setting time, compressive strength, hydration products, microstructure, and pore structure. The experimental results showed that adding SCTs compound enabled the generation of S-rich expansive products, such as ettringite, sodium sulfate, and gypsum. Moreover, nano-sized spherical particles were formed and well-distributed in pores or micro-cracks in the microstructure of AAS mortars. Consequently, AAS mortars with SCTs compound developed higher compressive strength at all ages than the blank ones, with an increase of 40.2-144.8% at 3 days, 29.4-115.7% at 7 days, and 29.3-136.3% at 28 days. Furthermore, AAS mortars with SCTs compounds enjoyed significant economic and environmental benefits, as demonstrated by cost-benefit and eco-efficiency analyses. The optimal sulfur content of the SCTs compound was found to be 15%.

Physico-chemical and extraction properties on alkali-treated Acacia pennata fiber.

The production of reinforced composite materials can generally benefit greatly from the use of natural cellulosic woody fibers as good sustainable resources. Natural plants like hemp, cotton, and bamboo are great options for knitters and crocheters looking to make eco-friendly goods. The current study examines the properties of natural fiber obtained from the stem of the Acacia pennata (AP) plant, as well as its basic physico-chemical, structural, thermal, and mechanical characteristics. The key goal of this work was to investigate how alkali treatment affected the AP fibers' morphology, chemical composition, tensile capabilities, morphological changes, structural changes, and thermal degradation (APFs). The SEM image and pXRD analyses support the improved surface roughness of the fiber, and that was seen after the alkaline treatment. From XRD analysis, the fiber crystallinity index (54.65%) was improved and it was connected to their SEM pictograms in comparison to untreated APF. Alkali-treated AP fibers include a higher percentage of chemical components including cellulose (51.38%) and ash (5.13%). Alkali-treated AP fibers have a lower amount of hemi-cellulose (30.30%), lignin (20.96%), pectin (8.77%), wax (0.12%), and moisture (13.44%) than untreated APF. Their low density and high cellulosic content will improve their ability to fiber matrices. The thermal behavior of AP fiber at various temperatures was demonstrated by TG-DTA analysis, and tensile strength was also investigated.

Modification of palm fiber with chitosan-AESO blend coating.

Natural fibers are available as an essential substitute for synthetic fiber in many applications. However, the sensitivity of Chinese Windmill Palm or Trachycarpus Fortune Fiber (TFF) to water causes low interfacial bonding between the matrix and the fiber and at the end reduces the mechanical properties of the composite product. Alkaline treatment improves mechanical properties and does not affect water absorption. Hence, additional treatment in the coating is required. This study uses alkaline treatment and coating modification using blended chitosan and Acrylated Epoxidized Soybean Oil (AESO). Blend coating between AESO and chitosan is performed to increase water absorption and mechanical properties. TFF water resistance improved significantly after the coating, with water absorption of the alkaline/blend coating-TFF of 3.98 % ± 0.52 and swell ability of 3.156 % ± 0.17. This indicated that blend coating had formed a cross-link of fiber and matrix after alkalization. Thus, the single fiber tensile strength increased due to the alkaline treatment, and water absorption decreased due to the coating. The combination of alkaline treatment and blend coating on TFF brings excellent properties, as shown by the increase in tensile strength in both single fiber test and composite.

Immobilization of chromium ore processing residue by alkali-activated composite binders and leaching characteristics.

Chromium ore processing residue (COPR) is classified as hazardous solid waste because of the leachable Cr(VI). Cementitious materials are often used to solidify and stabilize heavy metals. However, most of them focus on the leaching concentration of particles after solidification and stabilization and lack research on leaching characteristics. This study investigated the leaching characteristics of heavy metals in three simulated environments (HJ557-2010, HJ/T299-2007, TCLP) after immobilizing COPR with composite binders. Industrial solid waste coal fly ash and lead-zinc smelting slag are used to prepare composite binders through alkali activation technology. Compressive strength, particle leaching toxicity, acid neutralization capability, and semi-dynamic leaching test are used to evaluate the performance of the solidified body. The solidified body can be applied to building materials or treated as general industrial waste. Heavy metals are mainly released from the matrix by surface washing at a low rate. The analysis results, including XRD, FTIR, and SEM-EDS, show that chemical binding and physical encapsulation are the main immobilizing mechanisms to realize the coordinated disposal of Zn and Cr(VI).

Effect of air pollution-controlled residue of a sewage sludge incinerator on the drying shrinkage and the pore structure of alkali-activated materials.

Recycling air pollution-controlled residues (APCR) generated from sewage sludge incinerators can be used for waste management, but the leaching of potentially toxic heavy metals from APCR poses environmental and human health issues. The present paper describes a procedure using APCR to produce alkali-activated materials and thereby realize their disposal. The effect of APCR on the compressive strength and drying shrinkage of the alkali-activated slag/glass powder was investigated. The pore structure characteristics were analyzed for clarifying its relationship with drying shrinkage. The results indicated that the drying shrinkage of the alkali-activated material was related to the mesopore volume. The drying shrinkage was slightly increased after the incorporation of the 10 % APCR, which was likely attributed to the high volume of mesopores compared to the 20 % APCR that lowered the drying shrinkage and compressive strength. This decrease in drying shrinkage was due to the recrystallization of sodium sulfate in the pore solution that can act as expansive agents and aggregates. The growth stress of the crystalline sodium sulfate within the matrix can offset the tension stress caused by the water loss. In addition, leaching studies using the SW-846 Method 1311 showed that recycling APCR into the alkali-activated system did not present a toxicity leaching risk or release unacceptable concentrations of heavy metals. The incorporation of waste APCR and waste glass can make AAMs a very promising and safe environmental technology.

Alkali-oxygen cooking coupled with ultrasonic etching for directly defibrillation of bagasse parenchyma cells into cellulose nanofibrils.

A scheme combining alkali­oxygen cooking and ultrasonic etching cleaning was developed for the short range preparation of CNF from bagasse pith, which has a soft tissue structure and is rich in parenchyma cells. This scheme expands the utilization path of sugar waste sucrose pulp. The effect of NaOH, O2, macromolecular carbohydrates, and lignin on subsequent ultrasonic etching was analyzed, and it was found that the degree of alkali­oxygen cooking was positively correlated with the difficulty of subsequent ultrasonic etching. The mechanism of ultrasonic nano-crystallization was found to be the bidirectional etching mode from the edge and surface cracks of the cell fragments by ultrasonic microjet in the microtopography of CNF. The optimum preparation scheme was obtained under the condition of 28 % NaOH content and 0.5 MPa O2, which solves the problem of low-value utilization of bagasse pith and environmental pollution, providing a new possibility for the source of CNF.

Effects of the Structure and Molecular Weight of Alkali-Oxygen Lignin Isolated from Rice Straw on the Growth of Maize Seedlings.

The abundant and low-cost features of lignin in combination with its natural activities make it a fascinating biopolymer for valorization, especially, in agriculture as an active plant growth regulator. However, the structure-activity relationship of lignin in regulating plant growth and metabolism remains unclear. In this work, rice-straw-based low-molecular-weight (LWM, 1860 Da) and high-molecular-weight (HMW, 6840 Da) alkali-oxygen lignins are structurally and comparatively investigated to understand their effects on the growth and metabolism of maize seedlings. The results indicate that LMW lignin at 150 mg·L-1 displays early growth stimulation in maize. Under the optimal concentration of LMW lignin (25 mg·L-1), the growth of maize shoot is ∼83% higher than that of the control one. Furthermore, LMW lignin also has a positive effect on the upregulation of photosynthetic pigment, carbohydrate, and protein synthesis. In contrast, HMW lignin shows an overall inhibitory effect on the above-mentioned biochemical parameters. Based on the structural characterization, LMW lignin contains a higher syringyl/guaiacyl ratio (0.78) and carboxyl content (1.64 mmol·g-1) than HMW lignin (0.43 and 1.27 mmol·g-1, respectively), which demonstrates that methoxyl and carboxyl content of lignin may play a decisive role in seedling growth.

Preparation of controlled low-strength materials from alkali-excited red mud-slag-iron tailings sand and a study of the reaction mechanism.

To address the low utilization of fines in iron tailings sand (IOTs), a controlled low-strength material (CLSM) was prepared from a combination of fine IOTs and red mud (RM) slag. The 7-day unconfined compressive strength (7-d UCS), slump and cost were used as evaluation indicators, and 16 sets of tests were designed with the Box-Behnken design (BBD) response surface method. X-ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM)-energy dispersive spectroscopy (EDS) were used to study the microscopic morphology and reaction mechanism of the CLSM samples made with the optimal ratios. The results show that the best matching ratio for the alkali-activated RM-slag-IOTs CLSM was a sand ratio of 0.797, an NaOH dose of 3.667% and a mass concentration of 80.657%, and the 7d-UCS, slump and cost indicators verified the feasibility of applying the CLSM to the base course of pavement. Alkali activation of the CLSM also showed that the RM-slag cementation system produced new substances. Internal calcium-silicate-hydrogel (C-S-H) and calcium-aluminosilicate-hydrogel (C-A-S-H) agglomerates were the main sources of strength, and hydration products were interwoven to form a dense structure with crystals as the framework and gels as fillers.

Alkali-Stable Anion Exchange Membranes Based on Poly(xanthene).

Poly(xanthene)s (PXs) carrying trimethylammonium, methylpiperidinium, and quinuclidinium cations were synthesized and studied as a new class of anion exchange membranes (AEMs). The polymers were prepared in a superacid-mediated polyhydroxyalkylation involving 4,4'-biphenol and 1-bromo-3-(trifluoroacetylphenyl)-propane, followed by quaternization reactions with the corresponding amines. The architecture with a rigid PX backbone decorated with cations via flexible alkyl spacer chains resulted in AEMs with high ionic conductivity, thermal stability and alkali-resistance. For example, hydroxide conductivities up to 129 mS cm-1 were reached at 80 °C, and all the AEMs showed excellent alkaline stability with less than 4% ionic loss after treatment in 2 M aq. NaOH at 90 °C during 720 h. Critically, the diaryl ether links of the PX backbone remained intact after the harsh alkaline treatment, as evidenced by both 1H NMR spectroscopy and thermogravimetry. Our combined findings suggest that PX AEMs are viable materials for application in alkaline fuel cells and electrolyzers.

Effects of different copper salts on the physicochemical properties, microstructure and intermolecular interactions of preserved egg white.

This study was conducted to investigate the effects of different copper salts on the physicochemical properties, microstructure and intermolecular interactions of preserved egg white (PEW) during pickling. With increased pickling time, the alkalinity of the pickling solution and the moisture of PEW pickled by three copper salts (CuSO4, CuCl2 and Cu(CH3COO)2) gradually decreased, while the pH showed dynamic trends. During the early stage of pickling, the viscosity of PEW changed dynamically. With the progress of pickling, the hardness and springiness of PEW increased gradually and the α-helix structure gradually transformed into a more stable ß-structure. The main forces that maintained PEW gel were ionic and disulfide bonds. In the early stage of pickling, the alkali penetration rate of CuCl2 pickled preserved eggs was faster, and better gel strength and network structure were observed, followed by CuSO4 and Cu(CH3COO)2, while there were no significant differences in the later stage of pickling.

The effect of alkali concentration on the properties of activated tungsten tailings.

The 7d unconfined compressive strength tests of alkali-activated tungsten tailings and the microscopic characteristics tests of scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) were conducted to investigate the effect of alkali-solid ratio on the properties of alkali-activated tungsten tailings. The test results indicate that the unconfined compressive strength of alkali-activated tungsten tailings increased with the alkali-solid ratio. However, the strength decreases slightly when the alkali-solid ratio is 12%. The microstructures of the gels generated in the alkali-activated tungsten tailings are affected by the alkali-solid ratio. The details are as follows: the microstructure is honeycomb in low alkali-solid ratio (7%, 8% and 10%), with N-A-S-H as its primary form, and flocculation in high alkali-solid ratio (14% and 15%), mainly in the form of C-A-S-H. When the alkali-solid ratio is at the medium level (12%), the microstructure is a small round bead, and the N-A-S-H is equivalent to the C-A-S-H. The more C-A-S-H content, the greater the strength. This study can provide a scientific basis and technical reference for the resource utilization of tungsten tailings.

Comprehensive insights into the impact of pretreatment on anaerobic digestion of waste active sludge from perspectives of organic matter composition, thermodynamics, and multi-omics.

Although various pretreatments have been applied to promote the anaerobic digestion of waste active sludge (WAS), the mechanisms regarding the impact of pretreatment on anaerobic digestion have not been well addressed. In this study, the effects of acid, alkali, and thermal pretreatments on anaerobic digestion of WAS were comprehensively investigated from the perspectives of organic matter composition, thermodynamics, and multi-omics. Results showed acid, alkali, and thermal pretreatments increased the methane production potential of WAS by 53.7%, 98.2%, and 101.8%, respectively, compared with the control. The protein secondary structure was disrupted after pretreatment, with a shift from α-helix and ß-sheet to random coil and antiparallel ß-sheet/aggregated strands. Thermodynamically, the WAS flocculation process was controlled by the short-range interfacial interactions described by the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory, which was positively correlated (R = 0.97, p < 0.05) with the organic matter solubilization of the WAS. After pretreatment, the flocculation energy barrier of pretreated WAS was 4.1 (acid), 7.0 (alkali) and 7.1 (thermal) times higher than that of the control group, respectively. Multi-omics analysis confirmed that pretreatment promoted amino acids (tryptophan, tyrosine, phenylalanine, aspartate, glutamate) metabolism, energy metabolism (ABC transporters) and vitamin metabolism. Moreover, the comparison of upregulated differentially expressed proteins (DEPs) revealed that for amino acid metabolism, thermal treatment had the best promotion effect; for carbohydrate metabolism, alkali treatment had the best promotion effect; and for lipid metabolism, acid treatment was more advantageous, resulting in different anaerobic digestion efficiencies. This study provides an in-depth understanding of the impact of different pretreatments on WAS anaerobic digestion and has practical implication for the choice of proper pretreatment technology for biosolids.

Optimizing the alkali treatment of cellulosic Himalayan nettle fibre for reinforcement in polymer composites.

The Himalayan nettle plant can yield strong and long bast fibre. In this study, the extracted fibres were treated with 3, 5, 7, and 10 wt% alkali solution and characterised the raw and treated fibres for chemical, morphological, physical, mechanical, and thermal properties. The objective is to find the optimized alkali concentration for fibre surface treatment to use as reinforcement in polymer composites. Results revealed that alkali treatment removed waxes, lignin, and hemicellulose from the surface and enhanced the fibre properties to make it compatible with the polymer matrix. However, alkali concentration affected the fibre properties significantly. 5 % alkali treatment resulted in a maximum crystallinity index (79.1 %), average roughness (26.8 nm), tensile strength (296.97 MPa), activation energy (181.33/180.97 kJ/mol) and initial temperature for stage II degradation (311.2 °C). This investigation concludes that 5 % is the optimized alkali concentration for surface treatment of the nettle fibre.

Mechanism of the amelioration of the protein digestibility of whole marinated eggs by strong alkali pickling: Physicochemical properties, gel structure, and proteomics.

Marinated egg is one of the traditional egg products in China; however, its low digestibility has limited its further industrial application. In this study, the mechanism involved in the amelioration of the protein digestibility of whole marinated eggs by strong alkali pickling was investigated. The results revealed that the water content of strong alkali-pickled whole marinated egg (SPME) exhibited an increasing trend during the alkali pickling process. Furthermore, as the pickling process progressed, the hardness, net charge, and ß-sheets of the SPME first increased and then decreased, and the stability of the secondary structure of the SPME gradually decreased. In addition, long-term strong alkali pickling damaged the gel properties and protein structure of SPME, which resulted in the degradation of the protein. Thus, the alkali pickling significantly enhanced the digestibility of the SPME protein and the number of peptides present in the enzymolysis product of SPME. In summary, strong alkali pickling effectively improved the protein digestibility of marinated egg.